There's been a ton of rumours swirling amid a fan-led campaign that Disney will eventually introduce a younger version of Luke portrayed by Sebastian Stan. Obi-Wan and Ahsoka talk about Anakin in The Clone Wars ( watch here), which shows the relationship between the three characters. One new theory is that the casting of Indira Varma could point to her portraying a younger version of Ahsoka. She was Anakin's former apprentice and feels more guilt about his turning into Darth Vader than anyone except for Obi-Wan himself. It wouldn't be shocking to see her included in the series, as she's close to the two main characters we know are going to be featured. “The Book of Boba Fett” Episode 2’s Major New Villains, Easter Eggs, & Coolest New Characterįeatured image: Ewan McGregor in “Obi-Wan Kenobi.” Courtesy Disney+.We know that Rosario Dawson's Ahsoka Tano is getting her own Disney+ show that's set around The Mandalorian, which is about 20 years after the show Obi-Wan Kenobi takes place. “Obi-Wan Kenobi” Series Reveals Poster, Cast & Release DateĬ-3P0 Actor Anthony Daniels Teases Fussy But Heroic Droid’s Return to “Star Wars” Legendary “Star Wars” Composer John Williams Wrote the “Obi-Wan Kenobi” Theme Song “Obi-Wan Kenobi” First Look Reveals Ewan McGregor’s Jedi Master & His Blue Lightsaber “Obi-Wan Kenobi” is executive-produced by Kathleen Kennedy, Michelle Rejwan, Deborah Chow, Ewan McGregor and Joby Harold.įor more on all things Star Wars on Disney+, check out these stories: Joining the cast are Moses Ingram, Joel Edgerton, Bonnie Piesse, Kumail Nanjiani, Indira Varma, Rupert Friend, O’Shea Jackson Jr., Sung Kang, Simone Kessell, and Benny Safdie. The series also marks the return of Hayden Christensen in the role of Darth Vader. The story begins 10 years after the dramatic events of “Star Wars: Revenge of the Sith” where Obi-Wan Kenobi faced his greatest defeat-the downfall and corruption of his best friend and Jedi apprentice, Anakin Skywalker, who turned to the dark side as evil Sith Lord Darth Vader. Here’s the official synopsis from Disney+: Obi-Wan Kenobi arrives on Disney+ on May 25, exactly 45-years to the day that the original Star Wars appeared in theaters. It’s also exciting to see the extremely talented Ingram in a meaty, mysterious role, as well as the always-excellent Joel Edgerton as Uncle Owen, a minor character in the Star Wars canon who will have a much larger part to play here.Ĭheck out the trailer below. Between the first-rate special effects to the return of McGregor in a role he was born to play, as well seeing Christensen finally get a chance to play Vader, rather than the striving, petulant Annakin, all equates to a series that looks incredibly promising. “The Jedi cannot help what they are,” we’re informed in the trailer, “their compassion leaves a trail.” It’s a trail that Obi-Wan will no doubt leave, and one that Reva will follow to the ends of the galaxy. Newcomer Moses Ingram, a breakout star from Netflix’s Queen’s Gambit, plays a new villain in the series, a force-sensitive Inquisitor named Reva. Bear in mind that in Revenge of the Sith, Annakin Skywalker murdered a room full of young Padawan warriors (Jedis-in-training for you not up to speed on your Star Wars lingo), and with so many of the Jedi dead or scattered to the galactic winds, Obi-Wan Kenobi is first on Darth Vader’s extermination list. Now, Obi-Wan has gone into hiding, while a young Darth Vader, at the behest of his master, Emperor Palpatine, begins his long, brutal quest at hunting down the last of Jedi and finishing them off once and for all. In Revenge of the Sith, Obi-Wan Kenobi was forced to fight, and maim, his former protegé. A distant figure approaches across the sands of Tatooine while the opening notes of a score that can only be from Star Wars introduce us, at long last, to our first look at Disney+’s upcoming series Obi-Wan Kenobi. That figure is, of course, Ewan McGregor’s Jedi master, who informs us at the top of the first official teaser trailer that “the fight is done…we lost.” Obi-Wan Kenobi takes place ten years after the events in George Lucas’s Revenge of the Sith, which finished Annakin Skywalker (Hayden Christensen)’s descent from promising young Jedi into Darth Vader.
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8 The covalent character of hydrogen bonding also has been described by Coulson as “covalent-ionic resonance” 9 and by several others, as well as from a valence bond perspective, as “three-center-four-electron” interactions. A hydrogen bond X-H…Y may be viewed as a donor–acceptor orbital interaction, in which a set of lone pairs on Y donate into the antibonding orbital of X-H. 7 These early depictions of hydrogen bonds were developed from Lewis’ theory 6 for valence and bonding and hinted at the covalent character (i.e., orbital interaction) of hydrogen bonds. They recognized that ammonium hydroxide ( Figure 2b) is another example in which the “ union is fairly strong,” explaining that “… the hydrogen nucleus held between two octets constitutes a weak bond.” Huggins proposed the term “ hydrogen bridges” to describe the sharing of an H atom between two molecules. They noted that ammonia readily adds a hydrogen, hydrogen chloride readily loses one, but water could add or lose a hydrogen, and therefore a hydrogen could be shared between two water molecules and bind two molecules together ( Figure 2a). In 1920, Latimer and Rodebush 1 (along with the unpublished works of Huggins a year earlier, Box 1) first related the idea of electronegativity and bond polarity to the sharing of a hydrogen atom between two atoms. Discussion focuses on how molecular structure affects hydrogen bond strength, and on showcasing selected applications of hydrogen bond design principles. Debates touched on but not discussed in detail include the physical origins of hydrogen bonds and the physical explanations of each design principle. This review presents an overview of hydrogen bond design principles, based on five structural features: electronegativity effects (Section 2), steric effects (Section 3), electrostatic effects (Section 4), π-conjugation effects (Section 5), and cooperativity effects (Section 6). These events happened at the height of early applications of crystallography in chemistry and set the stage for the discovery of many hydrogen bond design principles (1990’s–2000’s), which are now routinely applied to areas of recognition, catalysis, and assembly in organic and supramolecular chemistry. Recognizing that a hydrogen nucleus shared between two atoms could largely influence the three dimensional structure of molecules and molecular fragments initiated a contentious race among multiple groups toward unveiling the double helix DNA structure (1953, Watson–Crick), 4 the α-helix structure (1951, Pauling–Corey–Branson) 5 and the β-sheet structure (1950, Pauling–Corey) 6 of proteins, along with surveys and developments of hydrogen bonding patterns in organic crystals (1950’s–1960’s). Lewis’ theory 3 of valence and chemical structures (1916)-so that the idea of a hydrogen bond could be conceived, and (b) the discovery of X-ray (1895)-so that a hydrogen bond, that is, close contact between proton-sharing atoms, could be observed. Leading up to the magnum opus of Latimer and Rodebush’s proposal of hydrogen bonding, two events in the early 1900’s steered the direction of hydrogen bond research during the first half of the 20th century: (a) G. Since the 1920 report of Latimer and Rodebush, 1 regularity in hydrogen bonding patterns were recognized, hydrogen bond design principles were developed, and it became possible to explain and imagine the structures and functions of many hydrogen bonding systems. 2 From the varying strengths and the directionality of hydrogen bonds, emerges the opportunity for chemical design. They can be as weak as less than a kilocalorie per mole, they can be as strong as half the association of a single C-C bond (e.g., the − interaction is about 40 kcal/mol), and the directionality of hydrogen bonds gives a clue to how molecules and molecular fragments might arrange in space. Hydrogen bonding interactions stand at the crossroad between weak noncovalent bonding and strong covalent bonding. Such an explanation amounts to saying that the hydrogen nucleus held between two octets constitutes a weak ‘bond’.” (Latimer WM and Rodebush WH, 1920) 1. a free pair of electrons on one water molecule might be able to exert sufficient force on a hydrogen held by a pair of electrons on another water molecule to bind the two molecules together. “Water…shows tendencies both to add and give up hydrogen, which are nearly balanced. Viber is a highly useful app that lets users save lots of money on calls. And all of these features are multiplatform, meaning they auto-sync between devices so you can carry on with chats on your smartphone that you’ve started on your Mac, and vice versa. The desktop version includes all the features of the original app, such as the option to make voice or video calls, or send stickers or other files in your chats. 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If you only wanted to know how to record a screen on Windows with audio, then you can stop right here. What more features can you use while recording your screen with audio? With a single click, the recording will stop and the video will get uploaded to your dashboard automatically. When you’re ready to stop the recording, click on the timer at the top bar of the screen. When you have done all of that, tap on that big blue button with Start Recording written all over it. If it’s only a specific area, then Custom size is the one for you. If you’re sure it’s only going to be a single window, then Record a Window is the right pick. If you want to record multiple windows, then you have to select Full screen recording. Step 5: Choose recording mode and ACTIONĬhoose the recording mode: Screen, Screen + Webcam, Webcam or Schedule your recordingĪlso choose the recording area. Keeping the system audio will not add value unless you’re playing an audio file on your computer. 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The mad painter does NOT like rats, as is evidenced by the hundreds of rat traps that will spontaneously appear and disappear in his fevered explorations. Inspired OCD achievement The artist's impression Collect a rat sketch The whole point of the game is finding clues as to why the painter has gone mad and what happened to his family, so of course you should be opening every last drawer and cabinet you find! After the 100 th drawer gets raided, you'll be awarded with the dubious honor of having “Inspired OCD!” Walking under the stacked chairs in the hallway in chapter four will also unlock the achievement.Īrtist's struggle achievement Inspired OCD Search 100 drawers and cabinets Most involve going into an obviously dangerous area or running towards your ghostly wife when you should be running away. There are several locations where you can embrace death and get the achievement to pop. It rings a bell achievement Artist's struggle Embrace death for the first time Open the lock to grab the ring and unlock this achievement. Light the candles to reveal numbers on the paintings, which are actually the code for the combination lock. In the first Layers Of Fear chapter you will come across a room with a candelabra, three paintings, and a chest with a combination lock. Scraps of love achievement It rings a bell Discover an echo from the past If you missed the photo memento, you can still get the achievement by picking up a hand-written letter discovered after you drop down through the floorboards near a fireplace, or any of the other memento collectibles later in the game. Open the left side and grab the photograph to unlock the achievement. The ring itself isn't the memento you need (that actually unlocks the “It rings a bell” achievement listed below). Head into the next room near the combination lock and you'll find a large cabinet with glass doors. One of the earliest can be discovered when you find the first locked combination chest containing a ring. There are a wide variety of different mementos you can pick up throughout the game to unlock this achievement. It's covered up for a reason achievement Scraps of love Find a memento of your family You can't miss it, as it's required to move forward in the story. This achievement unlocks as soon as you pull the white drape off your unfinished painting at the end of the game's first segment. Wanderer achievement It's covered up for a reason Get working on the Magnum Opus Unless you are going for a speed run and not exploring all the nooks and crannies, you'll probably get this one to pop not long into the second chapter. This one is simple to achieve as you'll get it just by exploring the mansion. Be sure to also check out our complete review of this minimalist but effectively frightening game, along with our Layers Of Fear tips and tricks walkthrough for the more difficult puzzles. 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Sticking with the single player for the time being, there is a lot of content to go at, with over 100 levels split over two chapters. The presentation is pretty much as you’d expect of an RTS, yet what about the gameplay? Well, it is split along two lines – that of the single player campaign and the multiplayer modes. The little mushrooms you control are pretty cute to be honest, and you almost feel bad for sending them up against other mushrooms, but they’re not to reason why and all that. But when the alien mushrooms (don’t ask!) capture the same structure, it shoots lasers instead. So should the red mushrooms, as an example, capture a tower, that tower will fire out cannonballs. In this arena there are a number of structures that can be captured, and in a nice touch, the structures change depending on which faction occupies them. Each battle that you take part in, in the single player or the much vaunted multiplayer (more on that later), takes place on a single screen, in an arena type setting. As you’d expect from a game that has found success as a mobile title, the graphics are small, but quite well detailed. With the reason for us going to war sorted, it’s time to examine the game in depth and what better way to start than with the presentation. It’s almost like conflict is inevitable or something… Not just any mushrooms, mind, but sentient mushrooms who can not only organise themselves into armies, but can utilise magic, forge weapons and then, inevitably, go to war with other, differently coloured mushrooms. After a while, as Jeff Goldblum says, “life finds a way” and mushrooms start to sprout. The world has been struck by a massive meteorite, and all life seems to have been destroyed. You don’t need to have played the original Mushroom Wars in order to get the most out of Mushroom Wars 2. |